300548-00-9

Upstream product

• 6160-65-2 1,1'-Thiocarbonyldiimidazole 
• 162119-07-5 (2S,3R,4R,5R)-2,3,4,6-Tetrakis-benzyloxy-5-hydroxy-hexanal O-methyl-oxime 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 

Downstream Products

• 112924-71-7 [1R-(1α,2β,3α,4β,5β)]-1-methoxyamino-2,3,4-tris(phenylmethoxy)-5-[(phenylmethoxy)methyl]cyclopentane 
• 112684-58-9 [1R-(1α,2β,3α,4β,5α)]-1-methoxyamino-2,3,4-tris(phenylmethoxy)-5-[(phenylmethoxy)methyl]cyclopentane 

Relevant academic research and scientific papers

Radical cyclization in heterocycle synthesis. Part 9: A novel synthesis of aminocyclitols and related compounds via stannyl radical cyclization of oxime ethers derived from sugars

Stannyl radical addition-cyclization of oxime ethers derived from D-glucose, D-galactose, and D-xylose proceeded smoothly to afford alkoxyamino alcohols which were effectively converted into two types of glycosidase inhibitors or its candidates such as aminocyclitols, 1-deoxynojirimycin, and 1-deoxygalactostatin via reductive ring-expansion of trans alkoxyamino alcohols. (C) 2000 Elsevier Science Ltd.