1126901-42-5Relevant academic research and scientific papers
A Solution-Processable meso-Phenyl-BODIPY-Based n-Channel Semiconductor with Enhanced Fluorescence Emission
Ozcan, Emrah,Ozdemir, Mehmet,Ho, Dongil,Zorlu, Yunus,Ozdemir, Resul,Kim, Choongik,Usta, Hakan,Cosut, Bunyemin
, p. 1423 - 1431 (2019)
The molecular design, synthesis, and characterization of an acceptor-donor-acceptor (A-D-A) semiconductor BDY-Ph-2T-Ph-BDY comprising a central phenyl-bithiophene-phenyl π-donor and BODIPY π-acceptor end-units is reported. The semiconductor shows an optic
Synthesis, electrochemical/photophysical properties and computational investigation of 3,5-dialkyl BODIPY fluorophores
Derin, Yavuz,Y?lmaz, Ra?it Fikret,Baydilek, ?brahim Halil,Atalay, Vildan Eniso?lu,?zdemir, Abdil,Tutar, Ahmet
, p. 130 - 135 (2018/06/14)
A series of 3,5 dimethyl and diethyl BODIPY with different substitutions at meso position are synthesized and characterized. Photophysical and electrochemical features of the 3,5 dialkyl BODIPY fluorophores are investigated using experimental and computational approaches. All fluorophores display absorption maxima around at 510 nm and emission maxima around at 520 nm which correspound to very narrow Stokes shift. Among the fluorophores, 3,5,8 alkylated BODIPYs are found to have high fluorescence quantum yield (1.00–0.93). 4-Bromophenyl group at meso position decreases fluorescence quantum yield of the dye while it increases with 4-methoxyphenyl group at meso position. The HOMO-LUMO energies of synthesized fluorophore compounds were calculated by B3LYP/6-31G(d,p) and B3LYP/6-311+G(d,p) levels in chloroform phase. Electron donating and accepting groups show increasing and decreasing effect on the band gaps of the fluorophores respectively.
Scope and limitations of the liebeskind-srogl cross-coupling reactions involving the biellmann BODIPY
Betancourt-Mendiola, Lourdes,Valois-Escamilla, Ismael,Arbeloa, Teresa,Ba?uelos, Jorge,López Arbeloa, I?igo,Flores-Rizo, Juan O.,Hu, Rongrong,Lager, Erik,Gómez-Durán, César F. A.,Belmonte-Vázquez, José L.,Martínez-González, Mayra R.,Arroyo, Ismael J.,Osorio-Martínez, Carlos A.,Alvarado-Martínez, Enrique,Urías-Benavides, Arlette,Gutiérrez-Ramos, Brenda D.,Tang, Ben Zhong,Pe?a-Cabrera, Eduardo
, p. 5771 - 5782 (2015/06/16)
Several new examples of meso-(het)arylBODIPY were prepared via the Liebeskind-Srogl (L-S) cross-coupling reaction of the Biellmann BODIPYs (1a,b) and aryl- and heteroarylboronic acids in good to excellent yield. It was shown that this reaction could be ca
Novel meso-Polyarylamine-BODIPY hybrids: Synthesis and study of their optical properties
Lager, Erik,Liu, Jianzhao,Aguilar-Aguilar, Angelica,Tang, Ben Zhong,Pena-Cabrera, Eduardo
supporting information; experimental part, p. 2053 - 2058 (2009/08/07)
A series of 14 meso-polyarylamine-BODIPY (borondipyrromethene) hybrids of the general structure A were synthesized. Two methods were used to prepare them. The first protocol involved a direct Liebeskind-Srogl cross-coupling of thiomethylbodipys 1-2 with a
