112701-63-0Relevant academic research and scientific papers
Synthesis and reactivity of α and β-chloro-α-phenylselanyl esters
Lebarillier, Loic,Outurquin, Francis,Paulmier, Claude
, p. 7495 - 7502 (2000)
Thermal decomposition of the dichloro-adducts derived from α-phenylselanylesters 1, 2 and 4 has been studied. N-Chloro-succinimide treatment of esters 2 was an efficient preparative method for α-chloro-α-phenylselanylesters 10 and α-chloro-α,β-unsaturated esters 11. Some transformations of esters 10 were achieved, α,β-Dichloro-α-phenylselanylesters 22 were prepared from β-chloro-α-phenylselanylesters 5 or by decomposition of the dichloroselenuranes 21 derived from esters 4. (C) 2000 Elsevier Science Ltd.
Electrophilic Addition of Benzeneselenenyl Chloride to Alkenes Bearing an Electron-withdrawing Substituent
Toshimitsu, Akio,Terao, Keiji,Uemura, Sakae
, p. 1059 - 1062 (2007/10/02)
Reaction of benzeneselenenyl chloride with alkenes bearing electron-withdrawing substituents was found to afford a mixture of regioisomeric adducts formed via the electrophilic addition of the phenylseleno group.The isomer distribution can be accounted for by postulating the interaction in the episelenonium ion intermediate of the phenylseleno group with the electron-withdrawing substituent.
