112712-18-2Relevant academic research and scientific papers
One-pot synthesis of alkoxyamine derivatives by reductive alkoxyamination with a 2-picoline-borane complex
Kawase, Yasushi,Yamagishi, Takehiro,Kutsuma, Teruo,Ueda, Kimio,Iwakuma, Takeo,Nakata, Tadashi,Yokomatsu, Tsutomu
experimental part, p. 463 - 470 (2009/06/08)
Reduction of oxime ethers with a 2-picoline-borane complex was examined to give alkoxyamine derivatives. The reduction was found to proceed in the presence of aqueous HCl in MeOH-AcOH. The method was extended to one-pot synthesis of alkoxyamine derivative
General combinatorial synthesis of tertiary amines on solid support. A novel conditional release strategy based on traceless linking at nitrogen
Gustafsson, Magnus,Olsson, Roger,Andersson, Carl-Magnus
, p. 133 - 136 (2007/10/03)
A novel solid phase synthesis of tertiary amines involving iodide-induced cleavage of the N-O bond of resin bound alkoxyammonium intermediates is described. The quaternary intermediates were assembled via sequential reductive aminations followed by alkylation. Cleavage from the solid support was induced by iodide ion or base, to afford the target tertiary amines in excellent purity.
BIS(TRI-n-BUTYLSTANNYL)BENZOPINACOLATE: PREPARATION AND USE AS A MEDIATOR OF INTERMOLECULAR FREE RADICAL REACTIONS
Hart, David J.,Krishnamurthy, Ramanarayanan,Pook, Lori M.,Seely, Franklin L.
, p. 7819 - 7822 (2007/10/02)
Bis(tri-n-butylstannyl)benzopinacolinate (2) serves as a thermal source of tri-n-butylstannyl radicals and mediates intermolecular coupling of selected alkyl halides to O-benzylformaldoxime and electron deficient olefins.A free radical non-chain mechanism is proposed for these reactions.
