1127562-52-0Relevant academic research and scientific papers
Direct arylations of electron-deficient (hetero)arenes with aryl or alkenyl tosylates and mesylates
Ackermann, Lutz,Fenner, Sabine
supporting information; experimental part, p. 430 - 432 (2011/02/28)
A palladium catalyst derived from the ligand X-Phos enabled generally applicable direct arylations of electron-deficient heteroarenes and arenes with aryl and alkenyl tosylates or mesylates.
Mechanistic analysis of azine N-oxide direct arylation: Evidence for a critical role of acetate in the Pd(OAc)2 precatalyst
Sun, Ho-Yan,Gorelsky, Serge I.,Stuart, David R.,Campeau, Louis-Charles,Fagnou, Keith
supporting information; experimental part, p. 8180 - 8189 (2011/03/17)
Detailed mechanistic studies on the palladium-catalyzed direct arylation of pyridine N-oxides are presented. The order of each reaction component is determined to provide a general mechanistic picture. The C-H bond cleaving step is examined in further det
Direct arylation of azine N-oxides with aryl triflates
Schipper, Derek J.,El-Salfiti, Mohamed,Whipp, Christopher J.,Fagnou, Keith
experimental part, p. 4977 - 4983 (2009/10/17)
Palladium catalyzed direct arylation of azine N-oxides using aryl triflates to afford the corresponding 2-aryl azine N-oxides is described. The reaction is carried out with a range of both N-oxides and aryl triflates. The arylation can be carried out in s
