112775-48-1Relevant academic research and scientific papers
ACETALS AS CHIRAL AUXILIARIES Part 4 Asymmetric synthesis of γ,δ-ethylenic aldehydes An approach to the California Red scale pheromone
Mangeney, P.,Alexakis, A.,Normant, J. F.
, p. 2363 - 2366 (2007/10/02)
Alkenyl copper - BF3 reagents, associated with tributylphosphine, react stereoselectively with chiral α, β-ethylenic acetals.A precursor of the California Red scale pheromone has been prepared.
DIASTEREOSELECTIVE CONJUGATE ADDITION TO CHIRAL α,β ETHYLENIC ACETALS
Mangeney, P.,Alexakis, A.,Normant, J. F.
, p. 3143 - 3146 (2007/10/02)
The phenyl copper reagent associated with Lewis acid (BF3) reacts regio (SN2') and stereoselectively with chiral α,β ethylenic acetals.
