1128193-20-3Relevant articles and documents
Palladium-Catalyzed Decarboxylative Ortho-Ethoxycarbonylation of O-Methyl Ketoximes and 2-Arylpyridines with Potassium Oxalate Monoester
Li, Zhong-Yuan,Wang, Guan-Wu
supporting information, p. 4866 - 4869 (2015/10/12)
A novel method for introducing an ester group via palladium-catalyzed ligand-directed C-H activation has been explored. The ortho-ethoxycarbonylation of O-methyl ketoximes proceeded smoothly with the nontoxic and easily handled reagent potassium oxalate monoester, affording the desired products in moderate to good yields. Furthermore, pyridine could also be employed as a directing group to obtain similar results in this transformation.
New reactivity of oxaziridine: Pd(II)-catalyzed aromatic C-H ethoxycarbonylation via C-C bond cleavage
Peng, Xingao,Zhu, Yingguang,Ramirez, Thomas A.,Zhao, Baoguo,Shi, Yian
supporting information; experimental part, p. 5244 - 5247 (2011/12/04)
A novel Pd(II)-catalyzed aromatic C-H ethoxycarbonylation with oxaziridine involving C-C bond cleavage is described. Various aromatic 2-phenylpyridines and related compounds as well as aryl ureas can be effectively ethoxycarbonylated. A catalytic cycle in
