112863-57-7Relevant academic research and scientific papers
Cobalt catalysed, copper assisted C(sp2)-P cross coupling
Ghosh, Tubai,Maity, Pintu,Kundu, Debasish,Ranu, Brindaban C.
, p. 9556 - 9564 (2016/11/11)
An efficient protocol for the cross coupling of styrenyl/aryl halides and H-phosphinate has been developed using a unique Co/Cu catalytic system in the absence of any additional ligand for the first time. A library of diversely functionalised styrenyl/ary
Nickel(II)-magnesium-catalyzed cross-coupling of 1,1-dibromo-1-alkenes with diphenylphosphine oxide: One-pot synthesis of (E)-1-alkenylphosphine oxides or bisphosphine oxides
Liu, Liu,Wang, Yulei,Zeng, Zhiping,Xu, Pengxiang,Gao, Yuxing,Yin, Yingwu,Zhao, Yufen
supporting information, p. 659 - 666 (2013/04/10)
A novel nickel(II)-magnesium-mediated cross-coupling of diphenylphosphine oxide with a variety of 1,1-dibromo-1-alkenes has been developed, which provides a powerful and general methodology for the stereoselective synthesis of various (E)-1-alkenylphosphine oxides or bisphosphine oxides, with operational simplicity of the procedure, good to high yields and broad substrate applicability. Mechanistic studies reveal that the reaction might involve a Hirao reduction, cross-coupling and Michael addition. Copyright
A Free Radical Addition-Fragmentation Reaction for the Preparation of Vinyl Sulfones and Phosphine Oxides
Keck, Gary E.,Byers, Jeffrey H.,Tafesh, Ahmed M.
, p. 1127 - 1128 (2007/10/02)
A free radical chain process is reported which gives vinyl sulfones or phosphine oxides in good to moderate yields under nonreducing conditions; the reaction involves irradiation of appropriate precursors to carbon-centered radicals with β-tri-n-butylstan
