90675-85-7

Upstream product

• 1374350-55-6 2-octen-2-yl diphenyl phosphate 
• 87436-98-4 oct-1-en-2-yl diphenyl phosphate 

Downstream Products

• 112863-57-7 (E)-non-1-en-1-yl diphenylphosphine oxide 
• 1429762-89-9 (Z)-non-1-en-1-yldiphenylphosphine oxide 

Relevant academic research and scientific papers

Ruthenium-catalyzed transformation of aryl and alkenyl triflates to halides

Aryl triflates were transformed to aryl bromides/iodides simply by treating them with LiBr/NaI and [Cp*Ru(MeCN)3]OTf. The ruthenium complex also catalyzed the transformation of alkenyl sulfonates and phosphates to alkenyl halides under mild conditions. Aryl and alkenyl triflates undergo oxidative addition to a ruthenium(II) complex to form η'1- arylruthenium and 1-ruthenacyclopropene intermediates, respectively, which are transformed to the corresponding halides.