1129-90-4

Usage

InChI:InChI=1/C12H20/c1-2-4-6-8-10-12-11-9-7-5-3-1/h1-10H2

Upstream product

• 375-72-4 Nonafluorobutanesulfonyl fluoride 
• 55314-44-8 [(cyclododec-1-en-1-yl)oxy](trimethyl)silane 

Downstream Products

• 931-05-5 α,α-dichloromethyltetrahydrofuran 
• 66891-27-8 2-cyclotridecyn-1-one 
• 1186296-54-7 1-[(1E)-1-ethylbut-1-en-1-yl]cyclododecene 
• 30651-70-8 (3E,5E)-4,5-diethylocta-3,5-diene 
• 36616-89-4 1,1'-bi(cyclododecene) 
• 15210-25-0 bicyclo[10.3.0]pentadec-1⁽¹²⁾-en-13-one 
• 1370727-55-1 3-ethyl 1-methyl 4-phenyl-5,6,7,8,9,10,11,12,13,14-decahydrobenzo[12]annulene-1,3-dicarboxylate 
• 1616776-25-0 13-phenyl-13-phosphabicyclo[10.3.0]pentadec-1⁽¹²⁾-ene 1-oxide 
• 1616776-29-4 13-phenyl-13-phosphabicyclo[10.3.0]pentadec-1⁽¹²⁾-ene 1-sulfide 
• 1616776-17-0 13-phenyl-13-phosphabicyclo[10.3.0]pentadec-1⁽¹²⁾-ene 
• 94865-47-1 cyclododecyl(phenyl)methanone 
• 947-04-6 2-azacyclotridecanone 

Relevant academic research and scientific papers

An expedient and stereoselective synthesis of alkenyl nonaflates from silyl enol ethers: Optimization, scope and limitations

The fluoride-catalysed reaction between silyl enol ethers 1 and nonafluorobutanesulfonyl fluoride (NfF) has been optimized, resulting in an expedient synthesis of the corresponding alkenyl nonaflates 3. Tetra-n-butylammonium fluoride, dried either with molecular sieves or with potassium fluoride, and potassium fluoride in the presence of dibenzo-18-crown-6 were the best and most practical catalysts for this process. The reaction allows the synthesis of a wide variety of cyclic and acyclic alkenyl nonaflates 3 in good to excellent yields. For E/Z isomeric alkenes the configuration of the double bond is essentially retained. Remarkably, enolates derived from methyl ketones also provide C-sulfonylation products 4 as a side product; the desired alkenyl nonaflates 31 and 3m could, however, be prepared in good yields by further optimization. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.