1616776-29-4Relevant academic research and scientific papers
Targeted synthesis of 2,3-disubstituted 2-phospholenes using catalytic cycloalumination of acetylenes
D'Yakonov, Vladimir A.,Makhamatkhanova, Alevtina L.,Agliullina, Rina A.,Tyumkina, Tat'Yana V.,Dzhemilev, Usein M.
, p. 3913 - 3915 (2014)
A preparative one-pot method for the synthesis of 2,3-dialkyl-substituted phosphol-2-enes by catalytic cycloalumination of symmetric acetylenes with AlEt3 catalyzed by Cp2ZrCl2 is developed. The reaction gives the corresponding aluminacyclopentenes, which then react in situ with phosphorus dihalides.
