112930-05-9Relevant academic research and scientific papers
Reactions involving fluoride ion. Part 44.1 Synthesis, and chemistry of aromatics with bulky perfluoroalkyl substituents
Chambers, Richard D.,Magron, Corinne,Sandford, Graham
, p. 283 - 290 (2007/10/03)
The observable perfluoroalkyl carbanion la, generated by addition of fluoride ion to perfluoroalkene 1, reacts efficiently with benzyl bromide, and a range of related derivatives 3a-g, and this provides methodology for the preparation of aromatic rings wi
Perfluoroalkylated amines, and polymers made therefrom
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, (2008/06/13)
1-[2,2-bis(trifluoromethyl)-3,3,4,4,5,5,5-heptafluoropentyl]-3,5-diaminobenzene and 1-[2,2-bis(trifluoromethyl)-3,3,4,4,5,5,5-heptafluoropentyl]-4-aminobenzene, as well as fluorinated polymers, preferably polyimides. The perfluoroalkyl group of these amin
PERFLUOROALKYLATION OF BENZYL BROMIDES USING PERFLUORO-2-METHYLPENT-2-ENE IN POTASSIUM FLUORIDE-DIMETHYLFORMAMIDE
Ikeda, Isao,Tsuji, Masanori,Okahara, Mitsuo
, p. 171 - 178 (2007/10/02)
A marked solvent effect was found in the reaction of perfluoro-2-methyl-2-pentene and benzyl bromides in the presence of fluoride anion to form α-(perfluoro-1,1-dimethylbutyl)-tolunitrile derivatives.Thus, potassium fluoride worked effectively as a fluori
