112930-06-0Relevant academic research and scientific papers
PERFLUOROALKYLATION OF BENZYL BROMIDES USING PERFLUORO-2-METHYLPENT-2-ENE IN POTASSIUM FLUORIDE-DIMETHYLFORMAMIDE
Ikeda, Isao,Tsuji, Masanori,Okahara, Mitsuo
, p. 171 - 178 (1987)
A marked solvent effect was found in the reaction of perfluoro-2-methyl-2-pentene and benzyl bromides in the presence of fluoride anion to form α-(perfluoro-1,1-dimethylbutyl)-tolunitrile derivatives.Thus, potassium fluoride worked effectively as a fluori
Reactions involving fluoride ion. Part 44.1 Synthesis, and chemistry of aromatics with bulky perfluoroalkyl substituents
Chambers, Richard D.,Magron, Corinne,Sandford, Graham
, p. 283 - 290 (2007/10/03)
The observable perfluoroalkyl carbanion la, generated by addition of fluoride ion to perfluoroalkene 1, reacts efficiently with benzyl bromide, and a range of related derivatives 3a-g, and this provides methodology for the preparation of aromatic rings wi
