1129491-16-2Relevant academic research and scientific papers
Highly Enantioselective Reactions of Cyclohexanone and β,γ-Unsaturated α-Keto Ester: The Tuning of Chemo-selectivities by Secondary and Primary Amine Catalysts
Wei, Jianwei,Guo, Wengang,Zhou, Xin,Du, Xin,Liu, Yan,Li, Can
, p. 985 - 990 (2014)
A series of of amphiphilic imidazole based secondary and primary amine catalysts were synthesized and shown to be very effective with an acid cocatalyst for the asymmetric reaction of cyclohexanone to β,γ-unsaturated α-keto ester. Interestingly, primary a
Highly enantioselective organocatalyzed construction of quaternary carbon centers via cross-aldol reaction of ketones in water
Zheng, Changwu,Wu, Yongyong,Wang, Xiaosheng,Zhao, Gang
supporting information; experimental part, p. 2690 - 2694 (2009/10/14)
The asymmetric construction of quaternary carbon centers via cross-aldol reactions of ketones with β,γ-unsaturated keto esters catalyzed by 4-(tert-butyldiphenylsilyloxy)-pyrrolidine-2-carboxylic acid in water is described. The adducts bearing two adjacen
