1129673-89-7Relevant academic research and scientific papers
SYNTHESIS OF STABLE C-(sup3)-CARBOMETALATED TRANSITION METAL COMPLEXES
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Page/Page column 17; 18, (2010/04/03)
The present invention provides a novel process for preparing carbometalated transition metal complexes, by reacting a transition metal complex having at least one conjugated diene ligand, with a dienophile, in a Diels-Alder cycloaddition reaction. In a particular embodiment, the invention discloses turning anthracene-based 9-C(sp2)-metalated complexes into C(sp3)-metalated ones by organic synthesis involving the Diels-Alder reaction.
