1129673-98-8

Upstream product

• 1356934-92-3 [C₁₆H₇(PPh₂)2(COOMe)2]Pt(trifluoroacetate) 
• 1129673-89-7 [PtCl(1,8-bis(diphenylphosphino)anthracene^(1-))] 
• 762-42-5 dimethyl acetylenedicarboxylate 

Downstream Products

• 1356934-92-3 [C₁₆H₇(PPh₂)2(COOMe)2]Pt(trifluoroacetate) 
• 1356934-87-6 [C₁₆H₇(PPh₂)2(COOMe)2]Pt(acetonitrile) tetrafluoroborate 

Relevant academic research and scientific papers

New PC(sp3)P pincer complexes of platinum and palladium

We describe the synthesis, characterization and properties of the new electrophilic palladium and platinum complexes bearing electron-rich PC(sp 3)P pincer ligands. We found that Lewis acidity of the compounds is low due to the strong σ-donation of the sp3-carbometalated ligand backbone.

SYNTHESIS OF STABLE C-(sup3)-CARBOMETALATED TRANSITION METAL COMPLEXES

The present invention provides a novel process for preparing carbometalated transition metal complexes, by reacting a transition metal complex having at least one conjugated diene ligand, with a dienophile, in a Diels-Alder cycloaddition reaction. In a particular embodiment, the invention discloses turning anthracene-based 9-C(sp2)-metalated complexes into C(sp3)-metalated ones by organic synthesis involving the Diels-Alder reaction.

Diels-Alder cycloaddition as a new approach toward stable PC(sp 3)P-metalated compounds

A straightforward synthetic route toward a new family of dibenzobarrelene-based cyclometalated compounds is described. The Royal Society of Chemistry.