112980-67-3

Upstream product

• 507-09-5 tiolacetic acid 
• 112489-56-2 methyl (Z)-(S)-4-phenylmethoxy-2-pentenoate 
• 119242-60-3 4-benzyloxy-(Z,4S)-2-penten-1-ol 
• 81445-44-5 (S)-2-(benzyloxy)propanal 
• 77396-98-6 (Z)-4-Benzyloxy-pent-2-en-1-ol 

Downstream Products

• 145914-28-9 (R)-2-((S)-1-Benzyloxy-ethyl)-but-3-ene-1-thiol 
• 145914-28-9 (S)-2-((S)-1-Benzyloxy-ethyl)-but-3-ene-1-thiol 
• 113034-40-5 (3R,3aS)-3-((S)-1-Benzyloxy-ethyl)-3a,4-dihydro-3H,6H-thieno[3,4-c]isoxazole 
• 113034-41-6 (3S,3aR)-3-((S)-1-Benzyloxy-ethyl)-3a,4-dihydro-3H,6H-thieno[3,4-c]isoxazole 
• 112994-33-9 (S)-4-benzyloxy-1-(2-nitroethylthio)-(Z)-2-pentene 

Relevant academic research and scientific papers

-THIA-WITTIG REARRANGEMENTS WITH A MARKED STARTING MATERIAL DEPENDENCE OF STEREOSELECTIVITY

-Thia-Wittig rearrangements were initiated (a) by Sn, Li exchange of stannyl sulfides type 5 (X = S) and (b) by reductive lithiation of S,S-acetals type 6 (X = S).Homoallyl thiols were obtained in yields between 49 and 96percent.E:Z selectivities of

INTRAMOLECULAR NITRILE OXIDE CYCLOADDITION ON CHIRAL OLEFINS : A STEREOCONTROLLED APPROACH TO β-KETOL PRECURSORS.

The intramolecular nitrile oxide cycloaddition reaction on (E) or (Z) olefins featuring a sulphur atom along the carbon chain connecting dipole and dipolarophile occurs with a poor to excellent anti stereoselectivity, which is mainly affected by the subst