113003-49-9Relevant articles and documents
The preparation of intercalating isoxazoles via a nitrile oxide cycloaddition
Mosher,Natale
, p. 779 - 781 (1995)
Pyridinium chlorochromate oxidation of 9-methylacridine (2) affords the corresponding aldehyde 3 in good yield. Conversion of the aldehyde to the hydroximinoyl chloride 5a was accomplished via reaction of the corresponding oxime with N-chlorosuccinimide. Dipolar addition to the enamine of ethylacetoacetate provided the corresponding isoxazoles 1 in good yield.
Highly regioselective 1,3-dipolar cycloaddition of 3′-O-propargyl guanosine with nitrile oxide: An efficient method for the synthesis of guanosine containing isoxazole moiety
Kore, Anilkumar R.,Senthilvelan, Annamalai,Shanmugasundaram, Muthian
, (2020/10/06)
The 1,3-dipolar cycloaddition reaction of 3′-O-propargyl guanosine with various in-situ generated nitrile oxides in the presence of DMF as a solvent is described. It is noteworthy that the reaction is highly regioselective that affords biologically import
(Z)-Stereospecific addition of glycosylmercaptans on nitrilium betaines. Synthesis of 1-S-glucopyranosyl arylthiohydroximates
Brochard,Joseph,Viaud,Rollin
, p. 1403 - 1414 (2007/10/02)
With a view to selecting new internal standards for HPLC analysis of glucosinolates, the synthesis of artificial desulfoglucosinolates 5 was carried out.