113019-40-2

Upstream product

• 7677-24-9 trimethylsilyl cyanide 
• 125411-99-6 ethyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside 
• 3866-62-4 2,3,4,6-tetra-O-benzyl-D-galactopyranosyl acetate 
• 6386-24-9 2,3,4,6-tetra-O-benzyl-D-galactopyranose 
• 4132-28-9 2,3,4,6-tetra-O-benzyl-α-D-galactopyranose 

Downstream Products

• 204069-49-8 (2',3',4',6'-tetra-O-benzyl-β-D-galactopyranosyl)methylamine 
• 474081-65-7 (2',3',4',6'-tetra-O-benzyl-β-D-galactopyranosyl)methylurea 
• 474081-88-4 (4S)-1-[(2',3',4',6'-tetra-O-benzyl-β-D-galactopyranosyl)methyl]-6-methyl-2-oxo-4-phenyl-1,2,3,4-tetrahydropyrimidine-5-carboxylic acid ethyl ester 
• 85230-61-1 1,3-diphenyl-2-(tetra-O-acetyl-2,6-anhydro-D-glycero-L-manno-heptosyl)-1,3-diphenylimidazolidine 
• 140397-46-2 (2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)methanal 
• 359017-25-7 ethyl 3-((2R,3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)-3-oxopropanoate 

Relevant academic research and scientific papers

A concise synthesis of α-glycosyl cyanides

A simple procedure has been developed for the synthesis of α-glycosyl cyanides: reactions of O-benzylated ethyl 1-thio-glycosides of L-fucose and D-glucose, with TMSCN and MeOTf in ether exclusively gave the corresponding α-glycosyl cyanides in good yield

A general approach to C-Acyl glycosides via palladium/copper Co-catalyzed coupling reaction of glycosyl carbothioates and arylboronic acids

A general and efficient approach to the synthesis of various C-acyl glycosides has been developed via Pd2(dba)3/CuTC co-catalyzed cross-coupling reaction of glycosyl carbothioates with arylboronic acids. The reaction showed a broad s

Addition of Organozinc Reagents to Glycopyranosyl Cyanides: Access to Keto Ester-C-glycosides or Unsaturated Acyl-C-glycosides

Addition of Reformatsky-type or allylic zinc reagents to 2,3,4,6-tetra-O-benzylglycopyranosyl cyanides led to keto ester-C-glycosides or unsaturated acyl-C-glycosides in moderate to excellent yields in the galactose, glucose, and mannose series.

Synthesis of Glycosyl Cyanides by the Reaction of 1-S-Phosphorothioates of Carbohydrates with Trimethylsilyl Cyanide

A new procedure is described for the synthesis of α,β-glycosyl cyanides by the reaction of per-O-benzylated S-α-D-glycopyranosyl phosphorothioates with trimethylsilyl cyanide in the presence of Lewis acid. Starting S-glycosyl phosphorothioates are prepare