1130348-23-0Relevant articles and documents
Assembly of π conjugated phosphole azahelicene derivatives into chiral coordination complexes: An experimental and theoretical study
Graule, Sebastien,Rudolph, Mark,Shen, Wenting,Gareth Williams,Lescop, Christophe,Autschbach, Jochen,Crassous, Jeanne,Reau, Regis
scheme or table, p. 5976 - 6005 (2010/09/08)
Aza[n]helicene phosphole derivatives have been prepared from aza[n]helicene diynes by the FaganNugent route. Their photophysical properties (UV/Vis absorption and emission behavior) have been evaluated. Their behavior as P,N chelates towards coordination to PdII and CuI has been investigated: metal-bis-(aza[n]helicene phosphole) assemblies are formed by a highly stereoselective coordination process, as demonstrated by X-ray crystallography. An aza[6]helicene phosphole bearing an enantiopure helicene part has been obtained, which allows the preparation of enantiopure Pd II and CuI complexes with original topologies and high molar rotation (MR) and circular dichroism (CD). The structure-property relationship established from the experimental data has been studied in detail by theoretical studies (TDDFT calculations of UV/Vis, CD, and MR). Aza[n]helicene phosphole derivatives show π conjugation extended over the entire molecule, and its influence on the MR of aza[6]helicene phosphole 5 c has been demonstrated. Finally, it has been shown that the nature of the metal (coordination geometry and electronic interaction) can have a great impact on the amplitude of the chiroptical properties in metal-bis(aza[n]helicene phosphole) assemblies.
