1130704-36-7Relevant articles and documents
Iron-catalysed Negishi coupling of benzyl halides and phosphates
Bedford, Robin B.,Huwe, Michael,Wilkinson, Mark C.
, p. 600 - 602 (2009)
Iron-based catalysts containing either 1,2-bis(diphenylphosphino)benzene or 1,3-bis(diphenylphosphino)propane give excellent activity and good selectivity in the Negishi coupling of aryl zinc reagents with a range of benzyl halides and phosphates. The Roy
Coupling of benzyl halides with aryl Grignard reagents catalyzed by iron(III) amine-bis(phenolate) complexes
Chard, Elliott F.,Dawe, Louise N.,Kozak, Christopher M.
, p. 32 - 39 (2013/06/27)
Reaction of benzylamino-N,N-bis(2-methylene-4,6-di-tert-amylphenol), H 2L1, with anhydrous ferric chloride in the presence of a base yields FeCl(THF)L1 (1). In the solid state, complex 1 exists as a monomeric iron(III) species with a distorted trigonal bipyramidal geometry. Complex 1 is an air-stable, non-hygroscopic, single-component catalyst for C-C cross-coupling of aryl Grignard reagents with benzyl halides, including chlorides. Moderate to good yields of cross-coupled products can be obtained in diethyl ether at room temperature. Preliminary investigations include the screening of electron-donating and electron-withdrawing groups on both the benzylic substrate and the aryl Grignard reagent.
Benzothiazolin-2-ylidene and azole mixed-ligand complexes of palladium
Yen, Swee Kuan,Koh, Lip Lin,Huynh, Han Vinh,Hor, T. S. Andy
experimental part, p. 4288 - 4297 (2010/01/31)
A series of mixed-ligand, mononuclear complexes trans[PdX 2(NSHC)(azole)] [NSHC = N,S-heterocyclic carbene; azole = imidazole, l-(2,4,6-trimethylphenyl)-1H-imidazole, benzimidazole, benzothiazole and benzoxazole] have been prepared and characterised by X-ray single-crystal diffrac-tion. These complexes catalyse the sp2-sp3 cross-coupling of fluoroaryl halides with arylboronic acid to give diarylmethanes with good yields and high turnovers, Wiley-VCH Verlag GmbH & Co. KGaA.
