113107-66-7Relevant academic research and scientific papers
Nickel-catalyzed electrochemical couplings of vinyl halides: Synthetic and stereochemical aspects
Cannes,Condon,Durandetti,Perichon,Nedelec
, p. 4575 - 4583 (2000)
Homo- and cross-coupling involving alkenyl halides have been performed efficiently using an electroassisted nickel-complex catalysis. Valuable product such as conjugated dienes, β,γ- or γ,δunsaturated esters, ketones, or nitriles, as well as alkenylated aryl compounds are thus prepared with high yields and high stereoselectivity. Partial isomerization is only observed in a few cases, when the alkenyl halide is involved in a late step of the catalytic cycle. This is the case in the preparation of (Z,Z)-1,3-diene.
Chemistry of O-Silylated Ketene Acetals. Novel Chemical Transformation of Vinyl Sulfoxides and Related Sulfoxides
Kita, Yasuyuki,Tamura, Osamu,Itoh, Fumio,Yasuda, Hitoshi,Miki, Takashi,Tamura, Yasumitsu
, p. 562 - 569 (2007/10/02)
It is shown that vinyl sulfoxides undergo two novel modes of reactions induced selectively by the O-silylated ketene acetal used.Vinyl sulfoxides, on treatment with bulky tert-butyldimethylsilyl ketene acetals, undergo a Michael-Pummerer-type reaction to
