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113123-37-8

2-Buten-1-ol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, (Z)- is a complex organic compound with the chemical formula C12H26O2Si. It is a chiral molecule, with the (Z)-configuration indicating the geometric arrangement of the double bond. 2-Buten-1-ol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, (Z)- is characterized by a 2-buten-1-ol backbone, which is a four-carbon chain with a hydroxyl group at the first carbon and a double bond between the second and third carbons. The 4-position is substituted with a silyl ether group, specifically a (1,1-dimethylethyl)dimethylsilyl group, which is a type of protecting group used in organic synthesis to shield hydroxyl groups from unwanted reactions. 2-Buten-1-ol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, (Z)- is of interest in the field of organic chemistry, particularly in the synthesis of complex molecules and the protection of functional groups during chemical transformations.

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  • 113123-37-8 Structure

  • Basic information

    1. Product Name: 2-Buten-1-ol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, (Z)-
    2. Synonyms:
    3. CAS NO:113123-37-8
    4. Molecular Formula: C10H22O2Si
    5. Molecular Weight: 202.369
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 113123-37-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-Buten-1-ol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, (Z)-(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-Buten-1-ol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, (Z)-(113123-37-8)
    11. EPA Substance Registry System: 2-Buten-1-ol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, (Z)-(113123-37-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 113123-37-8(Hazardous Substances Data)

113123-37-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 113123-37-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,3,1,2 and 3 respectively; the second part has 2 digits, 3 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 113123-37:
(8*1)+(7*1)+(6*3)+(5*1)+(4*2)+(3*3)+(2*3)+(1*7)=68
68 % 10 = 8
So 113123-37-8 is a valid CAS Registry Number.

113123-37-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-[tert-butyl(dimethyl)silyl]oxybut-2-en-1-ol

1.2 Other means of identification

Product number -
Other names 2-Buten-1-ol,4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:113123-37-8 SDS

113123-37-8Upstream product

113123-37-8Relevant articles and documents

Deprotection of a silyl group with mesoporous silica

Itoh, Akichika,Kodama, Tomohiro,Masaki, Yukio

, p. 861 - 864 (2007)

The triethylsilyl (TES) group of silyl ethers of several types is selectively and easily removed in the presence of a t-butyldimethylsilyl (TBDMS) group with a mesoporous silica MCM-41/MeOH heterogeneous system. Comparison of the efficiency was carried out among several solvents, and among such promoters as common zeolites and ion-exchange resins. Furthermore, FSM-16, another mesoporous silica, was examined for the possibility of recycling by re-calcination at 400°C after the reaction.

Selective deprotection of triethylsilyl group in the presence of t-butyldimethylsilyl group with MCM-41/MeOH heterogeneous system

Itoh, Akichika,Kodama, Tomohiro,Masaki, Yukio

, p. 357 - 359 (2007/10/03)

Triethylsilyl (TES) group of silyl ethers of several types is selectively and easily removed in the presence of t-butyldimethylsilyl group (TBS) with a mesoporous silica MCM-41/MeOH heterogeneous system. Comparison of the efficiency was carried out among several solvents, and among such promoters as common zeolites and ion-exchange resins. Thieme Stuttgart.

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