113124-75-7Relevant academic research and scientific papers
Ketene Claisen rearrangement of camphor-derived 1,3-oxathianes: Complete control of tertiary and quaternary stereogenic centres
Aggarwal, Varinder K.,Lattanzi, Alessandra,Fuentes, Daniel
, p. 2534 - 2535 (2007/10/03)
Dichloroketene reacts, via a [3,3]-sigmatropic rearrangement, with camphor-derived 1,3-oxathianes of α,β-unsaturated aldehydes to give macrocyclic thiolactones in high yield and with complete transfer of chirality. The rearrangement is stereospecific.
