113138-62-8Relevant academic research and scientific papers
A Convenient Synthesis of Fluorine-Containing Highly-Substituted Furans through New Fluoride Ion-Catalyzed Reaction of 1-Alkyl-F-1-alkenyl Phosphates
Kuroboshi, Manabu,Shinozaki, Takao,Ishihara, Takashi,Ando, Teiichi
, p. 1621 - 1622 (1987)
1-Alkyl-F-1-alkenyl phosphates, easily prepared from alkyl F-alkyl ketones and sodium diethyl phosphite, underwent the dephosphorylation followed by cyclocondensation in the presence of a fluoride ion catalyst and triethylamine at ambient temperature to g
Highly Effective Dephosphorylation of F-1-Alkenyl Phosphates with Copper Halide-Lithium Aluminium Hydride Reagent: A New Access to 1-Hydryl-F-alkyl Ketones from F-Alkyl Ketones
Ishihara, Takashi,Kuroboshi, Manabu
, p. 113 - 118 (2007/10/02)
1-Substituted F-1-alkenyl phosphates, readily available from F-alkyl ketones and diethyl phosphite, undergo the dephosphorylation by the action of copper(I) or copper(II) bromide and lithium aluminium hydride at -78 deg C followed by hydrolysis to give th
