113138-61-7Relevant academic research and scientific papers
A NEW EFFICIENT METHOD FOR THE GENERATION OF F-ALKYL KETONE METAL ENOLATES BY USING COPPER(II) BROMIDE-LITHIUM ALUMINIUM HYDRIDE REAGENT AND THEIR ALDOL REACTION WITH CARBONYL COMPOUNDS
Kuroboshi, Manabu,Okada, Yoshiji,Ishihara, Takashi,Ando, Teiichi
, p. 3501 - 3504 (1987)
1-Substituted F-1-alkenyl phosphates, readily prepared from F-alkyl ketones end sodium diethyl phosphite, were treated with copper(II) bromide-lithium aluminium hydride reagent at -30 degC to generate in situ F-alkyl ketone aluminium enolates, which under
A New Effective and Convenient Route to Fluorinated Nitrogen Heterocyclic Compounds by the Use of Enol Phosphates Derived from F-Alkyl Ketones
Ishihara, Takashi,Okada, Yoshiji,Kuroboshi, Manabu,Shinozaki, Takao,Ando, Teiichi
, p. 819 - 822 (2007/10/02)
The treatment of F-alkyl ketones with sodium diethyl phosphite in tetrahydrofuran at -10 to 0 deg C gave high yields of 1-substituted F-1-alkenyl phosphates, which readily reacted with amidine of hydrazine derivatives at room temperature to afford the cor
