1131544-86-9Relevant academic research and scientific papers
A scheme of the stepwise reaction of diphenylchlorophosphine with N,N-dialkylformamides in the presence of NaI
Morgalyuk,Strelkova
, p. 2096 - 2101 (2011)
On an example of DMF was proposed and experimentally verified stepwise reaction scheme of the reaction of diphenylchlorophosphine with N,N-dialkylformamides. The first stage is autocatalytic reaction of the synthesis of (diphenylphosphoryl)(N,N-dialkylami
Stoichiometry of the reaction of diphenylchlorophosphine with dimethylformamide in the presence of NaI
Morgalyuk,Petrovskii,Lysenko,Nifant'Ev
experimental part, p. 100 - 105 (2010/05/01)
Stoichiometric relations of initial compounds and reaction products in the synthesis of N,N-dialkyl-(diphenylphosphinomethylene)iminium are established; the second reaction product is diphenylphosphinic iodide. Bringing triphenylphosphine into the reaction increases the N,N- dialkyl(diphenylphosphinomethylene)-iminium yield approximately twice. One of the reaction intermediates is shown to be iododiphenylphosphine. The reaction can be regarded as disproportionation.
