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1352709-73-9

(diphenylphosphoryl)(N,N-dimethylamino)chloromethane is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1352709-73-9 Structure

  • Basic information

    1. Product Name: (diphenylphosphoryl)(N,N-dimethylamino)chloromethane
    2. Synonyms: (diphenylphosphoryl)(N,N-dimethylamino)chloromethane
    3. CAS NO:1352709-73-9
    4. Molecular Formula:
    5. Molecular Weight: 293.733
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1352709-73-9.mol
    9. Article Data: 5

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (diphenylphosphoryl)(N,N-dimethylamino)chloromethane(CAS DataBase Reference)
    10. NIST Chemistry Reference: (diphenylphosphoryl)(N,N-dimethylamino)chloromethane(1352709-73-9)
    11. EPA Substance Registry System: (diphenylphosphoryl)(N,N-dimethylamino)chloromethane(1352709-73-9)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1352709-73-9(Hazardous Substances Data)

1352709-73-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1352709-73-9 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,5,2,7,0 and 9 respectively; the second part has 2 digits, 7 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1352709-73:
(9*1)+(8*3)+(7*5)+(6*2)+(5*7)+(4*0)+(3*9)+(2*7)+(1*3)=159
159 % 10 = 9
So 1352709-73-9 is a valid CAS Registry Number.

1352709-73-9Relevant articles and documents

Ambident reactivity of chloro(dialkylamino)-(diphenylphosphinoyl)methanes

Morgalyuk, Vasilii Petrovich,Strelkova, Tat'Yana Vladimirovna,Nifant'Ev, Eduard Eugenievich

experimental part, p. 93 - 100 (2012/03/07)

The chemical properties of chloro(dialkylamino)(diphenylphosphinoyl) methanes have been studied using the simplest compound of this series, chloro(dimethylamino)(diphenylphosphinoyl)methane, as an example. Chloro- (dimethylamino)(diphenylphosphinoyl)methane shows ambident reactivity when reacting with electrophiles and nucleophiles depending on coreactant nature, it behaves as either electrophilic substrate or phosphorus nucleophile. This fact can be explained by its dissociation in solutions with both C-Cl bond cleavage to give (dimethylamino)- (diphenylphosphinoyl)methyl cation and Cl- anion and C-P bond cleavage to form chloro(dimethylamino)methyl cation and diphenylphosphinite anion. The capability of chloro(dimethylamino) (diphenylphosphinoyl)methane to produce spontaneously Ph2PO-anion allows us to recommend application in organic and organophosphorus synthesis as a synthetic equivalent (synthon) of diphenylphosphinite anion.

Synthesis of polyfunctionalized methylphosphine oxides

Morgalyuk,Strelkova,Nifant'Ev

, p. 380 - 385 (2013/06/05)

N,N-Dialkylamino(diphenylphosphoryl)chloromethanes, a new type of organophosphorus compounds, were synthesized. On dissolving in polar and low polar solvents, N,N-dialkylamino(diphenylphosphoryl)chloromethanes dissociate spontaneously with the P - C bond cleavage to form the diphenylphosphinite anion Ph2PO-. This was confirmed by the reaction of N,N-dimethylamino(diphenylphosphoryl)chloromethane with electrophilic substrates to form the corresponding addition or substitution products of Ph 2PO-. The capability of spontaneous generating the diphenylphosphinite anion considers accessible N,N- dimethylamino(diphenylphosphoryl)chloromethane as a synthetic equivalent of the diphenylphosphinite anion.

A scheme of the stepwise reaction of diphenylchlorophosphine with N,N-dialkylformamides in the presence of NaI

Morgalyuk,Strelkova

experimental part, p. 2096 - 2101 (2012/03/12)

On an example of DMF was proposed and experimentally verified stepwise reaction scheme of the reaction of diphenylchlorophosphine with N,N-dialkylformamides. The first stage is autocatalytic reaction of the synthesis of (diphenylphosphoryl)(N,N-dialkylami

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