113157-88-3

Upstream product

• 113157-82-7 2-(4-Bromo-phenylazo)-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-ol 
• 113157-89-4 3-Chloro-benzoic acid 2-(4-bromo-phenylazo)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 113157-91-8 N-(4-Bromo-phenyl)-N'-[1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylidene]-hydrazine 
• 137329-17-0 2-(4-Bromo-phenylazo)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl-hydroperoxide 

Relevant academic research and scientific papers

Involvement of the intramolecular ionic reaction in the steric compression-assisted reaction (stecar) concept, rearrangement of bornyl α-azo benzoate into lactam

The importance of the polarization and ionic reaction phenomena in the steric compression-assisted reaction (STECAR) concept is described.

Novel Thermal Deoxygenation in Bornyl α-Azohydroperoxide to Give Camphor Hydrazone. A Retro-ene Reaction Assisted by the Steric Compression Effect

Camphor hydrazone, its dimer, and oxygen are generated from bornyl α-azohydroperoxide by thermal reaction accompanied by several other products.The retro-ene elimination mechanism is proposed.