113157-91-8

Upstream product

• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 
• 589-21-9 (4-bromophenyl)hydrazine 
• 137329-17-0 2-(4-Bromo-phenylazo)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl-hydroperoxide 

Downstream Products

• 14579-97-6 2-acetyl-1-(4-bromophenyl)hydrazine 
• 113157-89-4 3-Chloro-benzoic acid 2-(4-bromo-phenylazo)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 
• 113157-88-3 2-(4-Bromo-phenylamino)-1,8,8-trimethyl-2-aza-bicyclo[3.2.1]octan-3-one 
• 113157-82-7 2-(4-Bromo-phenylazo)-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-ol 

Relevant academic research and scientific papers

The stecar (steric compression-assisted reaction) concept. Ionic deoxygenation reaction via intramolecular proton shift in bornyl α-azohydroperoxide to give camphor hydrazone

The study on the primary kinetic isotope effect for the thermal deoxygenation reaction in bornyl α-azohydroperoxide confirmed the importance of the intramolecular ionic reaction phenomenon in the STECAR concept.

Novel Thermal Deoxygenation in Bornyl α-Azohydroperoxide to Give Camphor Hydrazone. A Retro-ene Reaction Assisted by the Steric Compression Effect

Camphor hydrazone, its dimer, and oxygen are generated from bornyl α-azohydroperoxide by thermal reaction accompanied by several other products.The retro-ene elimination mechanism is proposed.