1132-58-7Relevant articles and documents
CONFORMATIONAL AND MOLECULAR STUDY OF THE 4-(2-CARBOXYETHYL)-1,2,3,4-TETRAHYDROCYCLOPENTINDOLE
Rodriguez, J. G.,Temprano, F.,Esteban-Calderon, C.,Martinez-Ripoll, M.,Garcia-Blanco, S.
, p. 3813 - 3823 (1985)
A conformational study of the title compound has been carried out in solution and solid states.The molecules are packed in the crystal forming a charge-transfer complex, where two different molecular pairs are found.Visible spectra data show two weak abso
1,3-dipolar cycloaddition of hydrazones with α-oxo-ketenes: A three-component stereoselective entry to pyrazolidinones and an original class of spirooxindoles
Presset, Marc,Mohanan, Kishor,Hamann, Marie,Coquerel, Yoann,Rodriguez, Jean
supporting information; experimental part, p. 4124 - 4127 (2011/10/04)
Stereodefined monocyclic, spirobicyclic, and bis-spirotricyclic pyrazolidin-3-ones can be prepared efficiently by a three-component reaction involving a 1,3-dipolar cycloaddition of azomethine imines obtained from hydrazones with α-oxo-ketene dipolarophiles generated in situ. The reaction allows the creation of four covalent bonds and two contiguous chiral quaternary centers with excellent diastereoselectivity in a single catalyst/additive-free, highly atom-economical transformation. From a fundamental point of view, the reaction introduces α-oxo-ketenes as effective dipolarophiles in 1,3-dipolar cycloadditions.
Electrochemical formation of methoxy- and cyano(phenylazo)alkanes from aldehyde and ketone phenylhydrazones
Okimoto, Mitsuhiro,Takahashi, Yukio,Kakuchi, Toyoji
, p. 2057 - 2063 (2007/10/03)
Several aldehyde and ketone phenylhydrazones were electrooxidized in MeOH. Electrooxidation in the presence of KI or tetraethylammonium p-toluenesulfonate as the supporting electrolyte afforded the corresponding methoxy(phenylazo)alkanes, whereas electrooxidation in the presence of KI, NaCN, and HOAc afforded the cyano(phenylazo)alkanes.