113200-26-3Relevant academic research and scientific papers
Oxiranes from Methylenation of the Ester Carbonyl Group by Diazomethane
Strazzolini, Paolo,Verardo, Giancarlo,Giumanini, Angelo G.
, p. 3321 - 3325 (2007/10/02)
Esters suitably substituted by electronegative groups were found to react with diazomethane with the anchimeric assistance of a ?-system or a trifluoromethyl group close to the ester oxygen to yield 2-alkoxy-2-substituted-oxiranes in good to excellent yields without catalysts.
ADDITION OF A METHYLENE GROUP ACROSS THE ESTER CARBONYL FUNCTION
Verardo, Giancarlo,Strazzolini, Paolo,Giumanini, Angelo C.
, p. 3011 - 3012 (2007/10/02)
Diazomethane in ethyl ether propmtly added to the carbonyl group of the phenyl trifluoroacetate to yield 2-phenoxy-2-trifluoromethyloxirane (2).
