1132096-26-4

Basic information

• Product Name: (-)-(3S,SS)-4-(Z)-3-n-butyl-5-phenyl-4-(p-tolylsulfinyl)pent-4-enal
• Synonyms: (-)-(3S,SS)-4-(Z)-3-n-butyl-5-phenyl-4-(p-tolylsulfinyl)pent-4-enal
• CAS NO: 1132096-26-4
• Molecular Weight: 354.513
• Mol File: 1132096-26-4.mol

Chemical Properties

• CAS DataBase Reference: (-)-(3S,SS)-4-(Z)-3-n-butyl-5-phenyl-4-(p-tolylsulfinyl)pent-4-enal(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(3S,SS)-4-(Z)-3-n-butyl-5-phenyl-4-(p-tolylsulfinyl)pent-4-enal(1132096-26-4)
• EPA Substance Registry System: (-)-(3S,SS)-4-(Z)-3-n-butyl-5-phenyl-4-(p-tolylsulfinyl)pent-4-enal(1132096-26-4)

Safety Data

• Hazardous Substances Data: 1132096-26-4(Hazardous Substances Data)

Upstream product

• 445282-38-2 (+)-(E)-3-[(E)-1-phenyl-2-(S^S)-(p-tolylsulfinyl)hept-2-en-1-(R)-oxy]methyl acrylate 
• 445282-37-1 (+)-(E)-1-phenyl-2-(S^S)-(p-tolylsulfinyl)hept-2-en-1-(R)-ol 

Relevant articles and documents

Asymmetric claisen rearrangements on chiral vinyl sulfoxides

Highly diastereoselective Claisen rearrangements of acyclic allyl vinyl ethers bearing a chiral sulfoxide at C-5 provide γ-δ-unsaturated aldehydes or ketones with up to two consecutive asymmetric centers in the molecule whilst preserving a useful vinyl su

Sulfinyl-mediated chirality transfer in diastereoselective claisen rearrangements

(Matrix Presented) The highly selective Claisen rearrangements of substrates bearing a sulfinyl moiety at C-5 allow for creation of up to two asymmetric centers and preserve a useful vinyl sulfoxide.