445282-38-2Relevant academic research and scientific papers
Sulfinyl-mediated chirality transfer in diastereoselective claisen rearrangements
Fernandez De La Pradilla, Roberto,Montero, Carlos,Tortosa, Mariola
, p. 2373 - 2376 (2002)
(Matrix Presented) The highly selective Claisen rearrangements of substrates bearing a sulfinyl moiety at C-5 allow for creation of up to two asymmetric centers and preserve a useful vinyl sulfoxide.
Asymmetric claisen rearrangements on chiral vinyl sulfoxides
De La Pradilla, Roberto Fernandez,Montero, Carlos,Tortosa, Mariola,Viso, Alma
supporting information; experimental part, p. 697 - 709 (2009/07/25)
Highly diastereoselective Claisen rearrangements of acyclic allyl vinyl ethers bearing a chiral sulfoxide at C-5 provide γ-δ-unsaturated aldehydes or ketones with up to two consecutive asymmetric centers in the molecule whilst preserving a useful vinyl su
