113261-66-8Relevant academic research and scientific papers
STEREOSPECIFIC SYNTHESIS OF THE LYTHGOE'S RING A ALDEHYDE FOR THE PREPARATION OF 1α-HYDROXYLATED TACHYSTEROLS AND CALCIFEROLS
Baggiolini, Enrico G.,Hennessy, Bernard M.,Iacobelli, Jerome A.,Uskokovic, Milan R.
, p. 2095 - 2098 (1987)
The dihydroxyaldehyde 1, an important intermediate for the synthesis of 1α-hydroxylated vitamin D derivatives via the corresponding tachysterol precursors, was prepared from (S)-(+)-carvone (6).The sequence involves as central step, the decarboxylation an
