1132652-56-2

Upstream product

• 42738-68-1 2-allylcyclohexane-1,3-dione 
• 123-38-6 propionaldehyde 
• 32774-70-2 2-allyl-3-hydroxycyclohex-2-en-1-one 
• 107-02-8 acrolein 
• 504-02-9 1,3-cylohexanedione 

Downstream Products

• 1132652-51-7 tert-butyl (E)-5-(1-allyl-2,6-dioxocyclohexyl)pent-2-enoate 
• 1416969-79-3 2-[(3E)-5-oxo-5-phenylpent-3-en-1-yl]-2-(prop-2-en-1-yl)cyclohexane-1,3-dione 
• 1416969-93-1 (4aS,5S,6R,8aR)-8a-allyl-5-benzoyl-4a-hydroxy-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)octahydronaphthalen-1(2H)-one 

Relevant academic research and scientific papers

Enantio- And Diastereoselective Construction of Contiguous Tetrasubstituted Chiral Carbons in Organocatalytic Oxadecalin Synthesis

The organocatalytic enantio- and diastereoselective cycloetherification of 1,3-cyclohexanedione-bearing enones involving the in situ generation of chiral cyanohydrins was developed. This transformation offers the first catalytic asymmetric approach to oxa

An easy route toward enantio-enriched polycyclic derivatives via an asymmetric domino conjugate reduction-aldol cyclization catalyzed by a chiral Cu(I) complex

A highly efficient reductive-aldol cyclization mediated by a chiral Cu(I) complex and an organosilane yielded to cyclic or polycyclic derivatives. An excellent control of the selectivities was reached in most cases (dr up to 100:0 and ee up to 95%). After

Efficient construction of polycyclic derivatives via a highly selective cui-catalyzed domino reductive-aldol cyclization

A versatile methodology for the diastereo-and enantioselective domino reductive-aldol cyclizations is reported. By using a copper (l)/diphosphane ligand, various five-and six-membered rings were generated with good to excellent diastereo-and enantioselect