113302-84-4

Upstream product

• 57772-50-6 2-amino-3-methylbenzyl alcohol 

Downstream Products

• 113302-67-3 2-azido-3-methylbenzaldehyde 
• 220630-34-2 2-azido-3-methylbenzyl chloride 
• 1416169-37-3 2-azido-1-methoxymethyl-3-methylbenzene 
• 1416169-45-3 C₂₃H₂₁NO 
• 1416169-51-1 4-methoxy-8-methyl-3,3-diphenyl-3,4-dihydroquinoline 
• 1416169-41-9 1-methoxymethyl-3-methyl-2-triphenylphosphoranylideneaminobenzene 
• 1416169-49-7 C₁₈H₁₉NO 
• 113302-73-1 2-azido-3-methylbenzaldehyde azine 
• 113302-85-5 2-<(2-azido-3-methylbenzylidene)amino>-3-methylindazole 
• 220630-50-2 Tris(2-azido-3-methylbenzyl)amine N-oxide 
• 220630-43-3 Tris-(2-azido-3-methyl-benzyl)-amine 
• 220630-68-2 Bis(2-azidobenzyl)(2-azido-3-methylbenzyl)amine N-oxide 
• 220630-67-1 Bis-(2-azido-benzyl)-(2-azido-3-methyl-benzyl)-amine 
• 220630-66-0 2-(2-Azido-3-methyl-benzyl)-isoindole-1,3-dione 

Relevant academic research and scientific papers

N-butyllithium-mediated reactions of 1-(2-azidoarylmethyl)-1H- benzotriazoles with alkyl halides

(Chemical Equation Presented) Treatment of 1-(2-azidoarylmethyl)-1H- benzotriazoles (6) with n-BuLi (2.5 equiv.) in THF at -78°C, followed by an addition of alkyl halides such as allyl, benzyl, and ethyl bromides with stirring for 2 h at room temperature afforded 2-(dialkylamino)-3-(benzotriazol- 1-yl)-2H-indazoles (8), 3-(benzotriazol-1-yl)-2H-indazoles (9), 2-[(benzotriazol-1-yl)methyl]arylamine (10), and 2-[(benzotriazol-1-yl)(alkyl) methyl]arylamine (11).

Synthesis and Complexing Properties of Macrocycles Incorporating 2,2'-Biindazolyl Binding Subunits

Substituted 2,2'-biindazoles 4 and 19-23 were prepared in 80-90percent yields by thermal decomposition of o,o'-diazido azines 13-18, which in turn were readily obtained from the corresponding 2-azidobenzaldehydes or 2-azidobenzophenones.The preference of