113302-67-3

Upstream product

• 113302-84-4 2-azido-3-methylbenzyl alcohol 
• 57772-50-6 2-amino-3-methylbenzyl alcohol 
• 5858-27-5 3-methyl-2-nitro-benzaldehyde 
• 109179-31-9 2-bromo-3-methyl-benzaldehyde 

Downstream Products

• 113302-73-1 2-azido-3-methylbenzaldehyde azine 
• 916664-21-6 2-azido-3-methylbenzaldehyde ehtylene acetal 
• 916664-33-0 (2-[1,3]dioxolan-2-yl-6-methyl-phenyl)-p-tolyl-carbodiimide 
• 916664-32-9 (4-chloro-phenyl)-(2-[1,3]dioxolan-2-yl-6-methyl-phenyl)-carbodiimide 
• 916664-31-8 (4-bromo-phenyl)-(2-[1,3]dioxolan-2-yl-6-methyl-phenyl)-carbodiimide 
• 916664-15-8 3-methyl-2-(triphenylphosphoranylideneamino)benzaldehyde ethylene acetal 
• 1279718-36-3 C₉H₁₀N₄O₃ 
• 1416168-91-6 2-azido-1-(dimethoxymethyl)-3-methylbenzene 
• 1416168-99-4 C₂₄H₂₃NO₂ 
• 1416168-95-0 1-(dimethoxymethyl)-3-methyl-2-triphenylphosphoranylideneaminobenzene 
• 1416169-07-7 4,4-dimethoxy-3,8-dimethyl-3-phenyl-3,4-dihydroquinoline 

Relevant academic research and scientific papers

PHOTOAFFINITY PROBES

Provided herein are compositions and methods for photoaffinity labeling of molecular targets. In particular, probes that specifically interact with cellular targets based on their affinity and are then covalently linked to the cellular target via a photor

AgSCF3/Na2S2O8-Promoted Trifluoromethylthiolation/Cyclization of o-Propargyl Arylazides/ o-Alkynyl Benzylazides: Synthesis of SCF3-Substituted Quinolines and Isoquinolines

A AgSCF3/Na2S2O8-promoted trifluoromethylthiolation/cascade cyclization of o-propargyl arylazides (or o-alkynyl benzylazides) triggered by a carbon-carbon triple bond is reported. This strategy provides the synthesis of valuable SCF3-substituted quinoline and isoquinoline systems via the construction of one C(sp2)-SCF3 bond and one C-N bond within one process.

Rh2(II)-catalyzed nitro-group migration reactions: Selective synthesis of 3-nitroindoles from β-nitro styryl azides

Rhodium carboxylate complexes (1 mol %) catalyze the migration of electron-withdrawing groups to selectively produce 3-substituted indoles from β-substituted styryl azides. The relative order of migratorial aptitude for this transformation is ester ? amide H sulfonyl benzoyl ? nitro.

Synthesis and Complexing Properties of Macrocycles Incorporating 2,2'-Biindazolyl Binding Subunits

Substituted 2,2'-biindazoles 4 and 19-23 were prepared in 80-90percent yields by thermal decomposition of o,o'-diazido azines 13-18, which in turn were readily obtained from the corresponding 2-azidobenzaldehydes or 2-azidobenzophenones.The preference of