113303-16-5

Basic information

• Product Name: Benzene, [(3,3-dimethyl-2-phenylbutyl)sulfonyl]-
• CAS NO: 113303-16-5
• Molecular Formula: C18H22O2S
• Molecular Weight: 302.437
• Mol File: 113303-16-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, [(3,3-dimethyl-2-phenylbutyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(3,3-dimethyl-2-phenylbutyl)sulfonyl]-(113303-16-5)
• EPA Substance Registry System: Benzene, [(3,3-dimethyl-2-phenylbutyl)sulfonyl]-(113303-16-5)

Safety Data

• Hazardous Substances Data: 113303-16-5(Hazardous Substances Data)

Upstream product

• 38442-51-2 tert-butylmercury chloride 
• 42599-24-6 E-styryl iodide 
• 16212-06-9 phenyl styryl sulfone 
• 677-22-5 tert-butylmagnesium chloride 
• 594-19-4 tert.-butyl lithium 

Relevant articles and documents

Electron Transfer Processes. Part 47. Reactions of Organometallic Reagents Involving Electron Transfer

Radical chain processes occur in conjugate addition reactions of 2-cycloalkenones with t-BuHgl2(1-), (t-Bu)2CuLi or (t-Bu)3ZnLi as judged by the relative reactivity of 2-cyclopentenone > 2-cyclohexenone and by the effect of CH2=CPh2 as a radical trap.On t

Reactions of Alkylmercurials with Heteroatom-Centered Acceptor Radicals

The relative reactivities of alkylmercury halides toward PhS., PhSe., or I. decrease drastically from R = tert-butyl to R = sec-alkyl to R = n-butyl, indicative that R. is formed in the rate-determining step in the attack of these radicals upon RHgCl.The alkyl radicals thus formed will enter into chain reactions in which a heteroatom-centered radical (A.) is regenerated from substrates such as RS-SR, ArSe-SeAr, ArTe-TeAr, PhSe-SO2Ar, Cl-SO2Ph; ZCH=CHA (A = Cl, I, SPh, SO2Ph); or PhCCHA (A = I, SPh, SO2Ph). β-Styrenyl (PhCH=CHA, Ph2C=CHA) and β-phenethynyl (PhCCA) systems with A = I, Br, SO2Ph also enter into chain reactions with mercury(II) salts with the ligands PhS, PhSe, PhSO2, or (EtO)2PO.The relative reactivities of a series of reagents toward t-Bu. and of PhCH=CHA, Ph2C=CHA, and PhCCA toward c-C6H11. are reported as well as the regioselectivity of t-Bu. attack observed for 1,2-disubstituted ethylenes (ZCH=CHA) with Z and A from the group Ph, Cl, Br, I, SO2Ph, SPh, Bu3Sn.Reactions of (E)- and (Z)-PhCH=CHI or MeO2CCH=CHI with t-Bu. or c-C6H11. occurred in a regioselective and stereospecific (retention) manner.Reactions of (E)- and (Z)-ClCH=CHCl occurred in a nonstereospecific manner in which the E/Z product ratio increased with the bulk of the attacking radical.A similar effect on the E/Z product ratios was observed for (Z)-MeO2CCH=CHCl.