113303-95-0Relevant academic research and scientific papers
AN EFFICIENT SYNTHESIS OF tert-ALKOXYETHYNES
Pericas, Miquel A.,Serratosa, Felix,Valenti, Eduard
, p. 2311 - 2316 (2007/10/02)
The synthesis of tert-butoxyethyne (1a) and (1-adamantyloxy)ethyne (1b) has been performed by a three step sequence starting from ethyl vinyl ether.Overall yields are 34 and 67percent, respectively.The process is insensitive to the steric hindrance of the tertiary alcohol used and can be conveniently modified for the preparation of 1-tert-alkoxy-1-alkynes in high yield, without isolation of the intermediate 1-tert-alkoxyethyne.
Photo-induced Alkoxybromination of Olefins by N,N'-Dibromo-2,5-piperazinedione
Sera, Akira,Yamada, Hiroshi,Itoh, Kuniaki
, p. 219 - 221 (2007/10/02)
Irradiation of N,N'-dibromo-2,5-piperazinedione in dichloromethane in the presence of an alcohol induced alkoxybromination of cyclohexene to give trans-1-bromo-2-alkoxycyclohexane in a good yield.The reaction was thought to proceed through an ionic mechanism.
