113307-70-3Relevant academic research and scientific papers
STEREOCHEMICAL INVESTIGATIONS. XXXVI. CONFORMATIONAL CHARACTERISTICS OF CYCLIC THIOKETALS OF 2-SUBSTITUTED CYCLOHEXANONES
Mursakulov, I. G.,Kasumov, N. K.,Ramazanov, E. A.,Movla-zade, S. A.,Samoshin, V. V.,Zefirov, N. S.
, p. 1321 - 1328 (2007/10/02)
The conformational equilibria in the cyclic thioketals of 2-substituted cyclohexanones were investigated by means of the averaged width of the signal for the methine proton in the PMR spectra.The dependence of the conformational characteristics on the structure of the thioketal group is interpreted in terms of steric and dipole-dipole interactions.
