113318-90-4

Basic information

• Product Name: Thiophene, 2,3,4,5-tetrachloro-1-[[(cyclohexyloxy)carbonyl]imino]-1,1-dihydro-
• CAS NO: 113318-90-4
• Molecular Formula: C11H11Cl4NO2S
• Molecular Weight: 363.092
• Mol File: 113318-90-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Thiophene, 2,3,4,5-tetrachloro-1-[[(cyclohexyloxy)carbonyl]imino]-1,1-dihydro-(CAS DataBase Reference)
• NIST Chemistry Reference: Thiophene, 2,3,4,5-tetrachloro-1-[[(cyclohexyloxy)carbonyl]imino]-1,1-dihydro-(113318-90-4)
• EPA Substance Registry System: Thiophene, 2,3,4,5-tetrachloro-1-[[(cyclohexyloxy)carbonyl]imino]-1,1-dihydro-(113318-90-4)

Safety Data

• Hazardous Substances Data: 113318-90-4(Hazardous Substances Data)

Upstream product

• 108-93-0 cyclohexanol 
• 6012-97-1 2,3,4,5-tetrachlorothiophene 
• 3422-06-8 cyclohexyl azidoformate 

Downstream Products

• 38898-70-3 cis-2-amino-cyclohexanol-⁽¹⁾ 
• 931-16-8 (+/-)-trans-2-aminocyclohexanol 

Relevant articles and documents

Alkoxycarbonylnitrenes as Selective Intramolecular CH-Insertion Reagents in Alicyclic Chemistry

Intramolecular CH-insertion of cyclohexyl, cis- and trans-4-t-butylcyclohexyl, and cis- and trans-2-methylcyclohexyl nitrenoformates have been studied.The nitrenes were generated by vapour-phase (spray) pyrolysis or solution thermolysis of the corresponding azides, or by photolysis of tetrachlorothienyl S,N-ylides derived from the azides.The product ratios were principally (and predictably) dependent upon reaction temperatures (and thus conformational equilibria), these varying in the range 10-500 deg C. 17-Substituted esterone-derived nitrenoformates inserted either into the 12β (from 17β) or 14 α (from 17α) CH sites while 17-derivatives with the nitrene on the end of a long inert group abstracted hydrogen from the streoid B-ring.