113321-58-7

Basic information

• Product Name: (2S,3S)-diethyl 2,3-bis(phenylmethoxy)succinate
• Synonyms: (2S,3S)-diethyl 2,3-bis(phenylmethoxy)succinate
• CAS NO: 113321-58-7
• Molecular Weight: 386.445
• Mol File: 113321-58-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (2S,3S)-diethyl 2,3-bis(phenylmethoxy)succinate(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-diethyl 2,3-bis(phenylmethoxy)succinate(113321-58-7)
• EPA Substance Registry System: (2S,3S)-diethyl 2,3-bis(phenylmethoxy)succinate(113321-58-7)

Safety Data

• Hazardous Substances Data: 113321-58-7(Hazardous Substances Data)

Upstream product

• 13811-71-7 diethyl (2S,3S)-tartrate 
• 100-39-0 benzyl bromide 

Downstream Products

• 116679-01-7 L-O,O-dibenzyltartaric acid 
• 1058023-73-6 (3S,4R)-3,4-bis(benzyloxy)tetrahydrofuran-2-ol 
• 171863-59-5 (((2R,3R)-2,3-bis(benzyloxy)pent-4-yn-1-yl)oxy)(tert-butyl)dimethylsilane 
• 162630-99-1 (2S,3R)-2,3-bis(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)butanal 
• 171622-74-5 (2R,3R)-2,3-bis(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)butan-1-ol 
• 113321-59-8 (2R,3R)-(-)-2,3-bis(phenylmethoxy)-1,4-bis<<(4-methylphenyl)sulfonyl>oxy>butane 
• 113303-32-5 (1R,2R)-(-)-1,2-bis(phenylmethoxy)-4,4-bis(phenylsulfonyl)cyclopentane 
• 113303-30-3 (2R,3R)-(-)-1,4-dibromo-2,3-bis(phenylmethoxy)butane 
• 113350-85-9 (1R,2R)-(-)-1,2-bis(phenylmethoxy)cyclopentane 
• 203389-77-9 Phosphoric acid dibenzyl ester (2R,3S)-2,3-bis-benzyloxy-4-oxo-butyl ester 
• 203389-79-1 Phosphoric acid dibenzyl ester (2R,3S)-2,3-bis-benzyloxy-4-oxo-pentyl ester 
• 203389-78-0 Phosphoric acid dibenzyl ester (2R,3R)-2,3-bis-benzyloxy-4-hydroxy-pentyl ester 
• 203389-76-8 Phosphoric acid dibenzyl ester (2R,3R)-2,3-bis-benzyloxy-4-hydroxy-butyl ester 
• 872130-26-2 phosphoric acid (2R,3S)-2,3-bis-benzyloxy-4,4-dimethoxy-butyl ester diphenyl ester 

Relevant articles and documents

An Efficient Synthesis of Both Enantiomers of trans-1,2-Cyclopentanediol and Their Conversion to Two Novel Bidentate Phosphite and Fluorophosphinite Ligands

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Correction to: Gold(I)-Catalyzed Domino Cyclizations of Diynes for the Synthesis of Functionalized Cyclohexenone Derivatives. Total Synthesis of (-)-Gabosine H and (-)-6-epi-Gabosine H (Organic Letters (2016) 18: 15 (3886-3889) DOI: 10.1021/acs.orglett.6b

The wrong enantiomers of (?)-gabosine H (5), (?)-epigabosine H (epi-5) and intermediates 6?10, 11a,b, and 12?22 were drawn in the Abstract, Table of Contents, and Schemes 2?6. The correct structural drawings for these compounds are provided. The corrected

Synthesis of exo-methylenedifluorocyclopentanes as precursors of fluorinated carbasugars by 5-exo-dig radical cyclization

The synthesis of polyhydroxylated 1,1-difluoro-5-methylenecyclopentanes is described. The sequence involves an addition of PhSeCF2TMS to a tartrate-derived aldehyde or its corresponding tert-butanesulfinylimines followed by a radical cyclization. The use of a benzyl protected substrate led to an unproductive 1,5-hydrogen transfer after cyclization but the desired compound was eventually obtained from the unprotected substrate. A hydroboration/oxidation sequence was investigated on these 1,1-difluoro-5- methylenecyclopentanes as it would provide fluorinated carbasugars, a new and promising class of glycomimetics. Unfortunately, this reaction was poorly efficient and its regioselectivity not the expected one.