113375-35-2Relevant academic research and scientific papers
Nitrogen Insertion to Bicycloheptanones; the Photo-Beckmann Rearrangement of Oximes of (+)-Fenchone and (+)-Camphor
Suginome, Hiroshi,Furukawa, Kenji,Orito, Kazuhiko
, p. 1004 - 1005 (1987)
The major products of the photolysis of the oximes of two natural bicycloheptanones, (+)-fenchone and (+)-camphor, in methanol are nearly equal amounts of two isomeric lactams arising from the photo-Beckmann rearrangement and the corresponding ring-opened amides.
Photoinduced Molecular Transformations. Part 119.1 Photochemical Nitrogen Insertion into Bicycloheptanones; the Photochemistry of Oximes of (+)-Fenchone and (+)-Camphor2
Suginome, Hiroshi,Furukawa, Kenji,Orito, Kazuhiko
, p. 917 - 921 (2007/10/02)
The photolysis of the oxime of (+)-fenchone in methanol gave a 1:1 ratio of two isomeric lactams, 1,4,4-trimethyl-2-azabicyclooctan-3-one (13percent) and its previously undescribed isomer, 1,4,4-trimethyl-3-azabicyclooctane-2-one (13percent)
