Nitrogen Insertion to Bicycloheptanones; the Photo-Beckmann Rearrangement of Oximes of (+)-Fenchone and (+)-Camphor

DOI: 10.1039/c39870001004

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Journal of the Chemical Society. Chemical communications p. 1004 - 1005 (1987)

Update date:2022-08-25

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Authors:

Suginome, Hiroshi

Furukawa, Kenji

Orito, Kazuhiko

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Article abstract of DOI:10.1039/c39870001004

The major products of the photolysis of the oximes of two natural bicyclo<2.2.1>heptanones, (+)-fenchone and (+)-camphor, in methanol are nearly equal amounts of two isomeric lactams arising from the photo-Beckmann rearrangement and the corresponding ring-opened amides.

Full text of DOI:10.1039/c39870001004

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