1134139-10-8Relevant articles and documents
Lutetium complexes with the 1,3-diphenylcyclopentadienyl ligand. Syntheses and molecular structures of the complexes {(Ph2C5H 3)Lu(C2Ph4)(THF)} and {(Ph2C 5H3)LuCl2(THF)3}
Roitershtein,Minyaev,Mikhailyuk,Lyssenko,Belyakov,Antipin
, p. 1978 - 1985 (2007)
The reaction of LuCl3(THF)3 with Na(1,3-Ph 2C5H3) followed by the in situ reaction with Na2[Ph4C2] produced (1,3-Ph2C 5H3)Lu(Ph4C2)(THF) (1). The structure of 1 was established by X-ray diffraction. In the crystal structure of 1, the bis-allyl η6-coordination of the tetraphenylethylene dianion to the lutetium cation was observed. The structures of (1,3-Ph 2C5H3)LuCl2(THF)3 and (C5H5)LuCl2(THF)3 were determined by X-ray diffraction.