113501-07-8Relevant academic research and scientific papers
Either γ-syn- Or γ-anti-selective palladium-catalysed carbonyl allylation by mixed (E)- and (Z)-l,3-dichloropropene with tin(II) halides
Masuyama, Yoshiro,Ito, Akihiro,Kurusu, Yasuhiko
, p. 315 - 316 (2007/10/03)
Palladium-catalysed carbonyl allylations by mixed (E)- and (Z)-1,3-dichloropropene with SnI2-Bu4NI and SnCl2 diastereoselectively produce syn and anti 1-substituted 2-chlorobut-3-en-1-ols, respectively. These are transform
Reactions of α-haloallyllithium derivatives with carbon, silicon, tin or boron halides and carbonyl compounds
Julia, Marc,Verpeaux, Jean-Noel,Zahneisen, Thomas
, p. 539 - 554 (2007/10/02)
A series of allylic halides have been converted into their α-carbanions with strong lithium bases, using different techniques.These have been compared in their reaction with various electrophiles leading to functionally substituted allyl derivatives.The influence of the counterion on the regio- and stereoselectivity has been investigated. allylic halides / α-halocarbanions / allylsilanes / allyltin derivatives / α-chlorohydrins / vinylepoxides / diastereoselectivity
STEREOSELECTIVE ADDITION OF α-CHLORO ALLYLIC CHROMIUM REAGENTS TO ALDEHYDES
Takai, Kazuhiko,Kataoka, Yasutaka,Utimoto, Kiitiro
, p. 4389 - 4392 (2007/10/02)
Treatment of a solution of 1,1-dichloro-2-butene and benzaldehyde with CrCl2 in THF-DMF at 25 deg C for 1 h gave threo-(Z)-4-chloro-2-methyl-1-phenyl-3-buten-1-ol in 96percent yield under high stereocontrol.
