113503-13-2Relevant academic research and scientific papers
FLUORIDE ANION INDUCED NOVEL REACTION OF α-(SULFONIO)KETONE TRIFLATE
Ito, Yoshihiko,Nakajo, Eiji,Sho, Katsuhiko,Tamao, Kohei
, p. 2247 - 2250 (1987)
α-(Phenylmethylsulfonio) ketone triflates (1) are treated with a suspension of KF in aprotic polar solvent to give dimeric 2-acylcyclobutanones (2), which are rearranged to γ,δ-unsaturated δ-valerolactones (3) by acid catalysts.
