113530-76-0Relevant academic research and scientific papers
THE CHEMISTRY OF CYCLOPENTADIENYL-RUTHENACYCLOPENTATRIENES: NOVEL CARBON MONOXIDE AND ISOCYANIDE INSERTION REACTIONS IN 5-C5H5)Ru(C4Ph2H2)Br>; CRYSTAL STRUCTURE OF 5-C5H5)Ru(η4-C5Ph2H2NBut)Br
Albers, Michel O.,De Waal, Dirk J.A.,Liles, David C.,Robinson, David J.,Singleton, Eric
, p. C29 - C32 (1987)
Reaction of the novel ruthenacyclopentatriene 5-C5H5)Ru(C4Ph2H2)Br> (1) with isocyanides gives the imino-2,5-diphenylcyclopentadiene complexes 5-C5H5)Ru(η4-C5Ph2H2NR)Br> (2, R = Me, Et, Cy, t-Bu, 2,6-Me2C6H3); a novel fluxional process involving phenyl substituent rotation and imino nitrogen inversion has been identifield for 2 (R = t-Bu, 2,6-Me2C6H3), the interpretation of which is supported by the X-ray crystal structure determination of 2 (R = t-Bu).
