Journal of Organometallic Chemistry p. C29 - C32 (1987)
Update date:2022-08-05
Topics:
Albers, Michel O.
De Waal, Dirk J.A.
Liles, David C.
Robinson, David J.
Singleton, Eric
Reaction of the novel ruthenacyclopentatriene <(η5-C5H5)Ru(C4Ph2H2)Br> (1) with isocyanides gives the imino-2,5-diphenylcyclopentadiene complexes <(η5-C5H5)Ru(η4-C5Ph2H2NR)Br> (2, R = Me, Et, Cy, t-Bu, 2,6-Me2C6H3); a novel fluxional process involving phenyl substituent rotation and imino nitrogen inversion has been identifield for 2 (R = t-Bu, 2,6-Me2C6H3), the interpretation of which is supported by the X-ray crystal structure determination of 2 (R = t-Bu).
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